A dimeric zinc(II) complex: bis[μ-1,2-bis(1,2,4-triazol-4-yl)ethane-κ2 N 1:N 1′]bis[dinitritozinc(II)]
نویسندگان
چکیده
The coordination geometry of the Zn(II) atom in the title complex, [Zn(2)(NO(2))(4)(C(6)H(8)N(6))(2)], is distorted octa-hedral, in which the Zn(II) atom is coordinated by two N atoms from the triazole rings of two symmetry-related 1,2-bis-(1,2,4-triazol-4-yl)ethane ligands and four O atoms from two nitrite ligands. Two Zn(II) atoms are bridged by two organic ligands, forming a centrosymmetric dimer. Weak C-H⋯N and C-H⋯O hydrogen bonds play an important role in the inter-molecular packing.
منابع مشابه
Bis[μ-1,2-bis(1,2,4-triazol-4-yl)ethane]bis[diiodidozinc(II)]
In the title dinuclear complex, [Zn(2)I(4)(C(6)H(8)N(6))(2)], two Zn(II )atoms are bridged by two 1,2-bis-(1,2,4-triazol-4-yl)ethane (btre) ligands, forming a centrosymmetric metallacycle. The coordination geometry of the Zn(II) ion is distorted tetra-hedral with the coordination sphere formed by two N atoms from the triazole rings of two symmetry-related btre ligands and two iodide ligands.
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